Article ID Journal Published Year Pages File Type
5289755 Tetrahedron Letters 2006 4 Pages PDF
Abstract
Diethyldimethylpyrazine-N,N′-dioxide (DEDMPDO) assembles with tetracyanoethylene (TCNE) into a 1:1 purple cocrystal giving layered networks cohered by DEDMPDO-TCNE donor-acceptor (DA) bonds. The NO-C intermolecular contacts are 2.81-3.02 Å and the two-dimensional DA bonded network is built from two unique donors and two unique acceptors within the assembly.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Preview
Pyrazine-N,N′-dioxide/tetracyanoethylene electron donor-acceptor bonding and the effect of donor steric demand and symmetry on the cocrystal assembly
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