Article ID Journal Published Year Pages File Type
5289768 Tetrahedron Letters 2006 4 Pages PDF
Abstract
A chiron approach starting with d-glucose, using a Grignard reaction and a Mitsunobu stereoinversion followed by stereoselective 1,2-syn reduction of the β-ketoester has been applied to execute the total synthesis.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Preview
Stereoselective total synthesis of (+)-cardiobutanolide and (+)-3-epi-cardiobutanolide from diacetone d-glucose
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