| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5290102 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
The dicationic ((R)-BINAP)palladium-catalyzed enantioselective aldol reaction of benzaldehyde with 1-phenyl-1-trimethylsilylethene has been reinvestigated regarding the reaction conditions in the presence of ((R)-BINAP)palladium chloride and AgSbF6 with 3Â Ã
molecular sieves. The simplified practical procedure with 1 mol % catalyst loading realized the high performance of 98% yield and 76% ee with reliable reproducibility.
Keywords
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Syun-ichi Kiyooka, Satomi Hosokawa, Sayaka Tsukasa,