Article ID Journal Published Year Pages File Type
52908 Catalysis Communications 2006 4 Pages PDF
Abstract

The change of substituent in the backbone of l-proline-derived sulfamide-amine alcohol ligand 3 provides chiral propargylic alcohols with the opposite configurations in significant enantioselectivities in the asymmetric addition of phenylacetylene to aldehydes. Meanwhile, the ligand 3 in combination with Ti(OiPr)4 could also afford the products with opposite absolute configuration in high yields.

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
Authors
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