Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5291184 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
Reaction of N-fluoropyridinium fluoride generated in situ with a series of isonitriles and diazo compounds led to the formation of the corresponding (pyridine-2-yl)-1H-1,2,3-triazoles in good yields (37-59%). Best outcome was consistently achieved with both aromatic isonitriles and stabilized diazo derivatives. The proposed reaction mechanism involves the intermediate formation of a highly reactive carbene species.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Alexander S. Kiselyov,