| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5291403 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
The described polyfunctional arylmagnesium reagents, resulting from the highly regioselective addition of magnesium phenylselenide to functionalized arynes, can be trapped by a range of electrophiles, yielding polyfunctional selenoethers in 45-85% yields. Furthermore, these Grignard reagents can be used in Negishi cross-coupling reactions with iodoarenes after transmetalation to the corresponding arylzinc compounds, furnishing functionalized biaryl products in 55-73% yields.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Wenwei Lin, Florian Ilgen, Paul Knochel,