Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5291419 | Tetrahedron Letters | 2008 | 4 Pages |
Abstract
A mechanistic study of organosulfide oxidation by H2O2, using a dinuclear manganese complex as the catalyst, has revealed an unusual switch in the philicity of the oxidant for the first and the second oxygen transfer steps; this switch has been exploited to tune selectivity for each of the products.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
John R. Lindsay Smith, Jane Murray, Paul H. Walton, Terry R. Lowdon,