Article ID Journal Published Year Pages File Type
5292608 Tetrahedron Letters 2005 4 Pages PDF
Abstract
Efficient and diastereocontrolled syntheses of natural lignans eupomatilone 2 (1) and 5 (2) are described. Biaryl coupling was achieved using Suzuki chemistry. The lactone moiety was constructed using allylmetal reagents, which were synthesized from Baylis-Hillman adducts. Allylindium reagents were found to be most effective.
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Physical Sciences and Engineering Chemistry Organic Chemistry
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The total synthesis of eupomatilones 2 and 5
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