Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
52950 | Catalysis Communications | 2009 | 4 Pages |
Abstract
Ring opening reaction of 1,2-epoxydodecane to the corresponding diacetate diester is described. Quaternary ammonium salts were found to be excellent catalysts for the acetylation reaction of the epoxide with acetic anhydride, where its activity was compared to different chloride salts. While in the presence of chloride salts no reactions were observed without activation, excellent yields (up to 100%) were achieved in the presence of quaternary ammonium salts. The effect of heterogeneous catalysts was compared to homogeneous ones.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Gabriella Fogassy, Catherine Pinel, Georges Gelbard,