Article ID Journal Published Year Pages File Type
52985 Catalysis Communications 2009 5 Pages PDF
Abstract

Two oxorhenium(V) complexes with bidentate phosphine ligands were synthesized and isolated as [ReOCl3(dppm)] 1 and [ReOCl3(dppp)] 2 [where dppm = 1,1-bis(diphenylphosphino) methane and dppp = 1,3-bis(diphenylphosphino) propane]. Complex 2 was structurally characterized. Both the complexes were used as catalysts in the epoxidation of olefins using NaHCO3 as co-catalyst and H2O2 as terminal oxidant.

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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