Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
52990 | Catalysis Communications | 2009 | 5 Pages |
Abstract
Catalytic properties of CuO supported on CexZr1−xO2 and WO3/CexZr1−xO2 with different Ce/Zr molar ratios are studied by using XRD, TPR, FT-IR and testing catalytic activities in low temperature CO + O2 reaction. The results show that with the addition of Zr, dispersion capacity and CO oxidation activities will decrease; H2 reduction and CO adsorption behaviors are also different. However, for copper oxide supported on CexZr1−xO2 pre-modified with WO3 full monolayer, i.e., CuO/WO3/CexZr1−xO2 samples, all these catalytic properties are similar and independent of the Ce/Zr molar ratios. Experiment results have been tentatively discussed by considering the change of surface structure of these supports.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Xiaowei Li, Haiqin Wan, Bin Liu, Lijuan Yang, Haiyang Zhu, Hongliang Chen, Xi Zhao, Keqin Sun, Lin Dong, Yi Chen,