| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5312263 | Tetrahedron Letters | 2017 | 4 Pages |
Abstract
Free radical cyclisation of the title halides 5a, 5b, 5c and 16 led to five-membered carbocycles in good yield. The main products are two isomeric deoxy compounds resulting from the extrusion of benzaldehyde. A three-step process [5-exo-digcyclisation, 1,5 hydrogen-atom-transfer, fragmentation] is proposed to explain their formation.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Isabelle Rochigneux, Marie-Laurence Fontanel, Jean-Claude Malanda, Alain Doutheau,