| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5322016 | Tetrahedron Letters | 2018 | 4 Pages |
Abstract
The reaction of allylic phosphates with the title organoaluminium reagent (PhMe2Si-AlEt2) provides allylsilanes in good yields. Cross coupling of enol phosphates with PhMe2Si-Mtl (Mtl = AlEt2 or MgMe) produces vinylsilanes regio- and stereoselectively in the presence of Pd(0) catalysts.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yasuhiro Okuda, Mitsuyoshi Sato, Koichiro Oshima, Hitosi Nozaki,