Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
53479 | Catalysis Today | 2015 | 4 Pages |
•Supported ionic liquid catalysts (SILCAs) are modified with Lewis acidic species.•Catalysts are applied in β-pinene oxide isomerisation reactions.•SILCAs are efficient catalysts for the transformation of β-pinene oxide into myrtanal.
The isomerisation of β-pinene oxide was studied over supported ionic liquid catalysts (SILCAs) consisting of Lewis acids in immobilized ionic liquid. SILCAs were demonstrated as efficient catalysts for the transformation of β-pinene oxide to myrtanal with the product distribution and activity being dependent on the nature of the ionic liquid and Lewis acid strength of catalytic species. With the catalyst ZnCl2/[N(3-OH-Pr)Py][NTf2]/ACC, the highest myrtanal molar yield obtained was 68%.
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