Article ID Journal Published Year Pages File Type
53498 Catalysis Today 2016 5 Pages PDF
Abstract

•Hydrolysis of xylan at temperatures between 70 and 90 °C and pH from 0.5 to 3.•Different liquid (HCl, H2SO4, triflouroacetic acid, oxalic acid) and solid (Smopex-101) catalysts.•Strong influence of the acid concentration and temperature, no influence of initial xylan concentration.•Substantial leaching with a heterogeneous catalyst Smopex-101.

The public interest in usage of lignocellulosic biomass as a renewable resource has grown strongly during the last decade. Hemicelluloses are the second most abundant constituents of wood biomass, but have yet received less attention, compared to cellulose. In this work hydrolysis of xylan, as an example of hemicelluloses, was studied at moderate temperatures between 70 and 90 °C and pH values ranging from 0.5 to 3 with different liquid (HCl, H2SO4, triflouroacetic acid, oxalic acid) and solid (Smopex-101) catalysts. Experimental results showed complete cleavage of xylan with xylose yields of up to 95%.

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Physical Sciences and Engineering Chemical Engineering Catalysis
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