Article ID Journal Published Year Pages File Type
5350878 Applied Surface Science 2014 6 Pages PDF
Abstract
In this study, a stable reactive sputtering process using a Ti-Nb alloy target was achieved by applying a plasma impedance feedback system. High-quality transparent conductive Nb-doped TiO2 (Nb:TiO2) films were fabricated with high reproducibility. The films were deposited on unheated substrate and subsequently annealed at 873 K under vacuum conditions (below 6.0 × 10−4 Pa) for 1 h. During reactive sputtering, the feedback system precisely controlled the oxidation of the target surface in the so-called transition region. The post-annealing process yielded polycrystalline Nb:TiO2 films whose lattice defects decreased with increasing Nb concentration. An extremely low resistivity (7.2 × 10−4 Ω cm) was achieved for Nb:TiO2 film with 60-70% transmittance in the visible region. The reactive sputtering using Ti-Nb alloys is considered to be a strong candidate for industrial-scale thin-film deposition. Furthermore, it can also control the metal-oxygen stoichiometry of Nb:TiO2 films precisely to achieve desirable properties for each industrial application.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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