| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5352350 | Applied Surface Science | 2013 | 11 Pages |
Abstract
This study investigated the interaction between the Al in the Zn bath and the surface oxides formed by selective oxidation on a 1.2Si-1.5Mn TRIP steel during hot-dip galvanizing. XPS and TEM were employed for characterization. The results indicated that the amorphous xMnO·SiO2 oxide could react with Al to form a Si-Mn-Al-containing oxide. The crystalline MnSiO3 and Mn2SiO4 oxides could be largely reduced by Al to form holes in the oxide film. Consequently, the steel covered by a layer of mixed xMnO·SiO2 and MnSiO3 could form a continuous Fe2Al5 inhibition layer and showed the highest galvanizability among the three samples examined.
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Authors
Kuang-Kuo Wang, Chiung-Wen Hsu, Liuwen Chang, Dershin Gan, Kuo-Cheng Yang,