Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5353110 | Applied Surface Science | 2016 | 10 Pages |
Abstract
Graphitized carbon (GC), nanodiamond (ND) and graphene (GE) supported Li4Ti5O12 (LTO) composites have been synthesized via a solid-state reaction, respectively. The particle sizes of LTO/GC, LTO/ND and LTO/GE are smaller than pure LTO. When tested as the anode for lithium ion batteries, the discharge capacities of LTO, LTO/GC, LTO/ND and LTO/GE composites are 100.1 mAh gâ1, 150.4 mAh gâ1, 90.4 mAh gâ1 and 218.3 mAh gâ1 at the current density of 175 mA gâ1 after 500 cycles. Their rate capacities retain 59.8%, 80.0%, 81.0% and 85.7% at the current density of 175 mA gâ1, 438 mA gâ1, 875 mA gâ1 and 175 mA gâ1, respectively. Moreover, the recovery rates of their rate capacities are 78.6%, 83.4%, 88.9% and 90.1% when returned to the current density of 175 mA gâ1, respectively. The reasons can be attributed to the synergistic effect between GC (ND and GE) and LTO as well as the features of the different carbon supports. This strategy, with the carbon constituting a good supporting structure, is an effective way to improve the cycling performance of anode materials for lithium ion batteries.
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Authors
Shuai Yang, Juan Miao, Qiufen Wang, Mengwei Lu, Jiufang Sun, Tao Wen,