Article ID Journal Published Year Pages File Type
5355707 Applied Surface Science 2011 5 Pages PDF
Abstract
► Raman spectroscopy analysis showed a strong dependence of the microstructure on the carbon content in the Ti-C-N films grown by RCBPLD. ► Thin films with a carbon content less than approximately 14 at% form a multiphase solid solution of TiN-TiCN. ► Increasing carbon content in the films promotes the formation of a nanocomposite of TiCN and TiC nanocrystals in an amorphous carbon matrix. ► The Raman features of the Ti-C-N films are very sensitive to carbon content suggesting that the observed Raman shifts could be used to estimate the carbon content in the films.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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