Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5357453 | Applied Surface Science | 2015 | 21 Pages |
Abstract
- Phenol is adsorbed on the structural-oxygen-deficient Ce-Mn-O(1Â 1Â 1) surface interacting with the Ce cation first neighbor to Mn dopant.
- The O-H of the phenol group bond is stretched up to 1.69Â Ã .
- Phenol interaction with the hydroxylated H-OH/Ce0.875Mn0.125O1.9375(1Â 1Â 1) surface is 0.51Â eV stronger than on the clean surface.
- The C6H5-O fraction is adsorbed in a bridge position between Mn and Ce cations with a tilt angle of 69.62° in agreement with IR data.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Oriana DÌAlessandro, Delfina GarcÃa Pintos, Alfredo Juan, Beatriz Irigoyen, Jorge Sambeth,