Article ID Journal Published Year Pages File Type
5359627 Applied Surface Science 2015 6 Pages PDF
Abstract

•Thermosensitive SiO2 nanoparticles were prepared with POEGMA via AGET-ATRP.•Reaction conditions were optimized.•Thermosensitive properties of SiO2-POEGMA particles were pronounced.

Thermosensitive poly(ethylene glycol) methyl ether methacrylate (POEGMA) was grafted on SiO2 nanoparticles using activators generated by electron transfer atom transfer radical polymerization (AGET-ATRP) technique. The effects of the amount of ligand, catalyst, ascorbic acid and monomer, as well as the reaction temperature and time were systematically investigated and optimized to get a high grafting density. The structure of the hybrid materials was characterized by Fourier transform infrared (FTIR) spectroscopy, and the morphology was characterized by transmission electron microscopy (TEM) observations. Thermosensitive properties of SiO2-POEGMA particles were investigated at different grafting densities by turbidity measurements.

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Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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