Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5359726 | Applied Surface Science | 2013 | 4 Pages |
Abstract
This paper investigates the effect of platinum catalyst thickness and morphology on the electrochemical surface area using electron microscopy and cyclic voltammetry. The roughness and porosity of platinum catalyst are varied by using different argon pressures during platinum sputter-deposition process. Lower argon pressure results in denser and smoother platinum films, which are confirmed by scanning electron microscopy and atomic force microscopy, respectively. The cyclic voltammetry is then used to quantify the catalytic activity of the films with various thickness and morphology. The electrochemical surface area extracted from the cyclic voltammetry shows that the current density is enhanced by 4-5 orders of magnitude through the formation of finite amount of porosity using a higher argon pressure (>60Â mTorr) compared to a highly dense film.
Related Topics
Physical Sciences and Engineering
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Physical and Theoretical Chemistry
Authors
Ikwhang Chang, Seunghee Woo, Min Hwan Lee, Joon Hyung Shim, Yuanzhe Piao, Suk Won Cha,