Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5361113 | Applied Surface Science | 2008 | 5 Pages |
Abstract
ZnO thin films were prepared on (1Â 1Â 1) silicon substrates by sublimation of zinc acetate dihydrate utilizing argon and oxygen as the carrier gas. ZnO films prepared using oxygen as the carrier gas exhibit a week near-band-edge (NBE) emission and strong orange-red deep level emission, while ZnO films prepared using argon as the carrier gas shows a strong NBE emission and weak deep level green emission. The NBE emission energy position can be controlled to vary from 3.241 to 3.137Â eV utilizing a combination of argon and oxygen as the carrier gas. Secondary ion mass spectroscopy analysis indicates that the relative concentration of carbon to hydrogen in the ZnO film remains constant, suggesting the presence of hydrocarbons. The concentration of hydrocarbon can be reduced by using oxygen in the carrier gas.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Liang-Chiun Chao, Meng-Yun Hsieh, Shih-Hsuan Yang,