Article ID Journal Published Year Pages File Type
5367014 Applied Surface Science 2011 5 Pages PDF
Abstract

The fabrication of high quality thin films of poly (vinylidene fluoride) embedded with multiwalled carbon nanotubes using pulsed laser deposition technique is reported. The prepared films were characterized for structural, morphology and dielectric properties. The morphology analysis revealed uniform dispersion of multiwalled carbon nanotubes throughout the polymer matrix. X-ray diffraction results suggested that the poly (vinylidene fluoride) film is in amorphous phase while addition of multiwalled carbon nanotubes showed presence of crystalline peaks in the nanocomposites films. It was interesting to note that the nanocomposite films exhibits significant enhancement of the ferroelectric β-phase as evidenced by the X-ray diffraction and Fourier transform infrared spectroscopy results. The dielectric analysis shows a remarkable enhancement in the dielectric permittivity of nanocomposites with lower loss and conductivity level. The results can be attributed to the formation of minicapacitor network and relatively higher percolation threshold in the nanocomposites.

► Pulsed laser deposition of thin film PVDF/MWCNT nanocomposites. ► Remarkable increase in dielectric permittivity at lower dielectric losses. ► Films show higher percolation threshold with lower conductivity. ► Enhancement of ferroelectric phase in PVDF/MWCNT nanocomposites.

Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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