Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5368440 | Applied Surface Science | 2007 | 6 Pages |
Abstract
Hydrothermal growth of hexagonal ZnO nanorods on the annealed titanate nanotube films is reported as a function of molar ratio of Zn(NO3)2 and methenamine (1:1-1:4). The molar ratio of 1:4 results in a dense and thinner rod in comparison with other molar ratios. Corn-like structures of the rods are believed to be due to the higher amine concentration. Raman peaks at 437 and 331Â cmâ1 are assigned to E2 and E2H-E2L modes. Near band gap edge and green photoluminescence emission indicates the structural and oxygen vacancy. O 1s peak is found built-up of sub-peaks at 530.62, 531.8 and 532.84Â eV corresponding to O2â on normal wurtzite structure and OH and oxygen vacancies of ZnO, respectively.
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Authors
Gil-Sung Kim, S.G. Ansari, Hyung-Kee Seo, Young-Soon Kim, O-Bong Yang, Hyung-Shik Shin,