Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5368605 | Applied Surface Science | 2010 | 6 Pages |
Abstract
A passive film was formed on electroless Ni-P coating (ENPC) in a bath of K2Cr2O7 30Â g/l. XPS and electrochemical methods were employed to analyze its chemical compositions and corrosion behaviors. The potentiodynamic polarization tests indicated the corrosion current of the passivated sample was 1/30 that of as-plated ENPC. The XPS analysis illustrated the film comprised Cr, Ni and O. The film thickness was evaluated to be a few nanometers according to the sputtering rate of Ar+ ion. High-resolution XPS spectra suggested that the detected Cr in film was in the form of trivalent compounds, Cr2O3 and Cr(OH)3.
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Authors
Songlin Mu, Ning Li, Deyu Li, Liying Xu,