Article ID Journal Published Year Pages File Type
5368605 Applied Surface Science 2010 6 Pages PDF
Abstract

A passive film was formed on electroless Ni-P coating (ENPC) in a bath of K2Cr2O7 30 g/l. XPS and electrochemical methods were employed to analyze its chemical compositions and corrosion behaviors. The potentiodynamic polarization tests indicated the corrosion current of the passivated sample was 1/30 that of as-plated ENPC. The XPS analysis illustrated the film comprised Cr, Ni and O. The film thickness was evaluated to be a few nanometers according to the sputtering rate of Ar+ ion. High-resolution XPS spectra suggested that the detected Cr in film was in the form of trivalent compounds, Cr2O3 and Cr(OH)3.

Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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