Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5368616 | Applied Surface Science | 2010 | 4 Pages |
Nitrogen-doped ZnO thin films have been prepared by reactive ion beam sputtering deposition utilizing a capillaritron ion source. X-ray diffraction (XRD) analysis of the as-deposited film exhibits a single strong ZnO (002) diffraction peak centred at 34.40°. Post-growth annealing causes increase of grain size and decrease of c-axis lattice constant. Micro-Raman spectroscopy analysis of the as-deposited film shows strong nitrogen-related local vibration mode at 275, 582, 640 and 720 cmâ1, whereas the E2 mode of ZnO at 436 cmâ1 can barely be identified. Annealing at 500-800 °C causes decrease of 275, 582, 640 and 720 cmâ1 and increase of 436 cmâ1 intensity, indicating out-diffusion of nitrogen and improvement of ZnO crystalline quality. Unlike un-doped ZnO, the surface roughness of nitrogen-doped ZnO deteriorates after annealing, which is also attributed to the out-diffusion of nitrogen. A nitrogen concentration of â¼1021/cm3 was observed while type conversion from n-type to p-type was not achieved, which is likely due to the formation of ZnI-NO or (N2)O that act as donor/double donors.