Article ID Journal Published Year Pages File Type
5372834 Chemical Physics 2016 12 Pages PDF
Abstract
We propose an extension of the Davydov Ansatz employing displaced squeezed states in the oscillator Hilbert space. The Dirac-Frenkel variational principle is used to derive the modified equations for the variational parameters. First numerical studies of the dynamics of the spin-boson model with a single bosonic degree of freedom reveal an overall improvement of the results as compared to the standard Davydov Ansatz.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
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