Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5372834 | Chemical Physics | 2016 | 12 Pages |
Abstract
We propose an extension of the Davydov Ansatz employing displaced squeezed states in the oscillator Hilbert space. The Dirac-Frenkel variational principle is used to derive the modified equations for the variational parameters. First numerical studies of the dynamics of the spin-boson model with a single bosonic degree of freedom reveal an overall improvement of the results as compared to the standard Davydov Ansatz.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Frank Grossmann, Michael Werther, Lipeng Chen, Yang Zhao,