| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5373754 | Chemical Physics | 2014 | 8 Pages |
Abstract
- Mechanism of PIET reaction process for the Rh101+/DEA system is investigated.
- The significant geometrical changes of the charge-transfer complex are explained.
- Forward Electron transfer from DEA to Rh101+â occurs with lifetime of 425-560Â fs.
- Backward electron transfer occurs with a time constant of 46.16-51.40Â ps.
- Intramolecular vibrational relaxation occurs with lifetime of 2.77-5.39Â ps.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Li-lin Jiang, Wei-long Liu, Yun-fei Song, Xing He, Yang Wang, Chang Wang, Hong-lin Wu, Fang Yang, Yan-qiang Yang,