| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5373869 | Chemical Physics | 2013 | 6 Pages |
Abstract
⺠Prepare two pairs of solutes, CpM(CO)3 and M2(CO)10 (M = Mn, Re) in alkane solutions. ⺠Solutes in each pair have similar volume, solvent interactions, but different mass. ⺠Rotational correlation times of these solutes are determined by narrow-band IR pump broad-band IR probe spectroscopy. ⺠Heavier substitutions have larger rotational correlation times. ⺠Mass effect on rotational correlation times is discussed.
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Authors
Son C. Nguyen, Justin P. Lomont, Charles B. Harris,