Article ID Journal Published Year Pages File Type
5373994 Chemical Physics 2013 11 Pages PDF
Abstract

- We found a parallel relationship between the two correlation lines of ln Δkisc vs. number of bonds.
- Effects of HOMO of the terminal chromophore appear as the intercept of the correlation lines.
- Difference of HOMO of the terminal porphyrin does not affect the interaction within the bridge part.
- An expression involving both HOMO and spacer dependence for EISC rate was derived.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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