Article ID Journal Published Year Pages File Type
5374164 Chemical Physics 2013 5 Pages PDF
Abstract
► Cooperativity in fluorinated -water systems has been analyzed for the first time. ► Highly fluorinated ethers show blue shift of CH bond with one water but red shifts with two water molecules. ► The relative magnitude of intra- and intermolecular hyperconjugations is found to determine the shift. ► Nice charge reciprocal effect is observed between the two water molecules.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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