Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5374164 | Chemical Physics | 2013 | 5 Pages |
Abstract
⺠Cooperativity in fluorinated -water systems has been analyzed for the first time. ⺠Highly fluorinated ethers show blue shift of CH bond with one water but red shifts with two water molecules. ⺠The relative magnitude of intra- and intermolecular hyperconjugations is found to determine the shift. ⺠Nice charge reciprocal effect is observed between the two water molecules.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Asit K. Chandra, Thérèse Zeegers-Huyskens,