Article ID Journal Published Year Pages File Type
5374422 Chemical Physics 2012 8 Pages PDF
Abstract
► The N2 molecule has 9510 states, including quasi-bound states. ► The lifetimes of such quasibound states are mostly long-lived. ► Rotational dissociation 1-2 orders of magnitude below vibrational dissociation. ► Contribution of quasi-bound states to the overall dissociation rate is negligible. ► At high temperatures, vibrational equilibration precedes rotational equilibration.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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