| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5374596 | Chemical Physics | 2012 | 9 Pages |
Abstract
⺠Kinetic and mechanism of the gas-phase thermolysis of tetroxane were determined. ⺠Gas chromatography and computational potential energy surfaces were performed. ⺠A mechanism in steps looked like the most probable mechanism. ⺠A spin-orbit coupling appeared at the singlet and triple diradical open structures. ⺠A non-adiabatic crossing from the singlet to the triplet state occurred.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Nelly Lidia Jorge, Jorge Marcelo Romero, André Grand, Alfonso Hernández-Laguna,