Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5374699 | Chemical Physics | 2011 | 34 Pages |
Abstract
⺠Two components maximizing either enthalpy (tetrahedral, low-density) or entropy (non-specific H-bonding, higher density). ⺠Interconvert discontinuously and ratio depends on temperature. ⺠Density fluctuations on 1 nm length scale. ⺠Increasing size in supercooled region. ⺠Connection to Widom line and 2nd critical point.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
A. Nilsson, L.G.M. Pettersson,