Article ID Journal Published Year Pages File Type
5375040 Chemical Physics 2010 9 Pages PDF
Abstract
We present an initial value representation for the semiclassical coherent state propagator based on complex trajectories. We map the complex phase space into a real one with twice as many dimensions and introduce initial valued trajectories in this double phase space. We use a procedure to eliminate non-contributing trajectories that allows for the automation of the entire calculation, rendering it simple. The resulting semiclassical formulas do not show divergences due to caustics and provide accurate results in short computational times.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
, , ,