Article ID Journal Published Year Pages File Type
5375125 Chemical Physics 2010 4 Pages PDF
Abstract
The superposition model has been used to investigate the crystal-field parameters of Cr3+ ion in ammonium lithium sulphate and then, zero-field splitting (ZFS) parameters D and E are calculated by the perturbation formulae. Both the ZFS parameters D and E evaluated theoretically are found to be in good agreement with the experimental values, Dexp and Eexp.
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Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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A theoretical analysis of zero-field splitting parameters of Cr3+ in ammonium lithium sulphate
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