Article ID Journal Published Year Pages File Type
5375294 Chemical Physics 2010 4 Pages PDF
Abstract
The coadsorption of alkalis (Na, K) with O on Cu(1 1 1) and Ni(1 1 1) surfaces was studied by vibrational measurements. We found that doping the Cu(1 1 1) surface with small amounts of alkalis reverses the energetic conditions for oxygen adsorption so as to render energetically favorable the population of subsurface sites. Such mechanism is not effective for the alkali-modified Ni(1 1 1) surface.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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