| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5375518 | Chemical Physics | 2009 | 5 Pages |
Abstract
The orientationally disordered (OD) mixed crystals of the two-component system 2-methyl-2-chloropropane (CCl(CH3)3)Â +Â bromotrichloromethane (CBrCl3) have been characterized. The continuous formation of OD face-centred cubic (FCC) mixed crystals and the existence of a large concentration domain of OD rhombohedral (R) mixed crystals together with a narrow [RÂ +Â FCC] two-phase equilibrium enable to get the thermodynamic properties of a virtual phase transition between a metastable R and the stable FCC phases for CCl(CH3)3 and to connect such a transition with the high-pressure stable phase for that compound, for which the symmetry is inferred.
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Authors
M. Barrio, J.Ll. Tamarit, R. Céolin, L.C. Pardo, Ph. Negrier, D. Mondieig,