Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5375614 | Chemical Physics | 2009 | 5 Pages |
Abstract
The data treatment in Thermally Stimulated Depolarisation Currents (TSDC) is generally based on the Debye decay function. Due to the nonexponentiality of the main relaxation in molecular glasses and amorphous polymers, this usual methodology has been criticized and the alternative use of the Kohlrausch function (stretched exponential) was suggested. In the present work it is shown that the original form of the Kohlrausch function is not adequate to the analysis of TSDC data. An alternative methodology is proposed.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Maria Teresa Viciosa, Gabriel Pires, Joaquim J. Moura Ramos,