| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5375812 | Chemical Physics | 2009 | 4 Pages |
Abstract
The vector correlations between products and reagents for the chemical reactions He+H2+/HD+ have been calculated by means of the quasi-classical trajectory (QCT) method at a collision energy of 1.0Â eV on the AQUILANTI surface [P. Palmieri, C. Puzzarini, V. Aquilanti, G. Capecchi, S. Cavalli, D. De Fazio, A. Aguilar, X. Gimenez, J.M. Lucas, Mol. Phys. 98 (2000) 1835]. The isotope effect on dynamical stereochemistry of the title reactions is discussed in detail. The pronounced isotopic effect may be ascribed to the difference of the mass factor in the two reactions.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Wen Wu Xu, Xin Guo Liu, Shi Xia Luan, Qing Gang Zhang,