Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5375877 | Chemical Physics | 2008 | 7 Pages |
Abstract
The spectroscopic properties of molecular trimers are studied within a model where three degenerate electronically excited states are coupled via dipole-dipole interactions. Taking a single vibrational degree of freedom for each monomer into account, this results in a non-adiabatic nuclear dynamic which determines features of the spectra. The cases of a cyclic and a linear coupling scheme are regarded and it is investigated how these different geometries influence the absorption and emission spectra.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Joachim Seibt, Volker Engel,