Article ID Journal Published Year Pages File Type
5376364 Chemical Physics 2007 10 Pages PDF
Abstract
The problem of turbulence in liquids is addressed by a recent theory of Brownian relativity. It relates the dynamics of the liquid molecules to the static properties of macromolecules dispersed in a polymer solution. As such, features of the random molecular motion in a turbulent fluid should also be recovered from a (simpler) statistical mechanics analysis of chain configurations. We took advantage of a covariant Vineyard-like approximation, formerly derived to get the van Hove's distribution functions in a dilute polymer solution. It points out an extended Gaussian statistics for correlated systems and a condition of probability conservation, exploited here to deal with a turbulently advected passive scalar by the partition function of a polymer network of given topology. Working with star polymers, a semi-heuristic closed-form expression for the anomalous scaling of passive structure exponents is derived. It agrees with earlier numerical simulations, encouraging the search of turbulent patterns “within” static chain configurations alone.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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