Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5376622 | Chemical Physics | 2007 | 7 Pages |
Abstract
We present a new semiclassical method that yields an approximation to the quantum mechanical wavefunction at a fixed, predetermined position. In the approach, a hierarchy of ODEs are solved along a trajectory with zero velocity. The new approximation is local, both literally and from a quantum mechanical point of view, in the sense that neighboring trajectories do not communicate with each other. The approach is readily extended to imaginary time propagation and is particularly useful for the calculation of quantities where only local information is required. We present two applications: the calculation of tunneling probabilities and the calculation of low energy eigenvalues. In both applications we obtain excellent agrement with the exact quantum mechanics, with a single trajectory propagation.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Yair Goldfarb, Ilan Degani, David J. Tannor,