| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5376911 | Chemical Physics | 2006 | 9 Pages |
Abstract
The present results lead to a complete and quantitative description of the conformational equilibrium including the radiative and radiationless relaxation rate parameters of the lowest excited states of the two rotamers. A simultaneous singlet and triplet mechanism for the geometrical photoisomerization, with an involvement of the former above room temperature only, seems to reasonably account for the experimental results. The role played by the rotamers in the photoreactive behaviour of (3TE)2B is also discussed.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
G. Bartocci, G. Ginocchietti, U. Mazzucato, A. Spalletti,