Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5377075 | Chemical Physics | 2006 | 18 Pages |
Abstract
IVCT solvatochromism studies on the diastereoisomeric forms of [{Ru(bpy)2}2(μ-dbneil)]5+ and [{Ru(pp)2}2(μ-bpm)]5+ {dbneil = dibenzoeilatin; pp = substituted derivatives of 2,2â²-bipyridine and 1,10-phenanthroline} revealed that the subtle and systematic changes in the nature of the clefts by the variation of the bridging ligand, and the judicious positioning of substituents on the terminal ligands, profoundly influenced the magnitude of the reorganizational energy contribution to the electron transfer barrier.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Deanna M. D'Alessandro, F. Richard Keene,