| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5379128 | Chemical Physics Letters | 2016 | 24 Pages |
Abstract
- First gas-phase spectroscopic study of a monomeric Grignard-type reagent, ClZnCH3.
- Synthetic evidence that ClZnCH3 forms by zinc insertion into the ClC bond.
- Estimate of the ionic character of the ZnCl bond from the chlorine quadrupole structure.
- Determination of the basic molecular structure of ClZnCH3 as a benchmark for theory.
- ZnCl bond length established for comparison with crystal structures.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
J. Min, M.P. Bucchino, K.M. Kilchenstein, L.M. Ziurys,