Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5379810 | Chemical Physics Letters | 2015 | 18 Pages |
Abstract
DFT calculations suggest that the reduction of 1+ to 2 is a metal-based process and the two complexes with donor-acceptor interaction between N2H2 and Fe centers have an antimagnetic coupling character. Such a reduction event decreased the acidity of NH bond and increased the basicity of N atoms of the diazene moiety.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Lun Luo, Si Chen, Yi Luo, Jingping Qu,