Article ID Journal Published Year Pages File Type
5379810 Chemical Physics Letters 2015 18 Pages PDF
Abstract
DFT calculations suggest that the reduction of 1+ to 2 is a metal-based process and the two complexes with donor-acceptor interaction between N2H2 and Fe centers have an antimagnetic coupling character. Such a reduction event decreased the acidity of NH bond and increased the basicity of N atoms of the diazene moiety.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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