Comparison of RC(O)OOH, RC(O)OOH and R(CO)OOH bond dissociation energies with RCOOH, RCOOH and RCOOH, R as phenyl, vinyl and alkyl groups

- Bond dissociation energies RC versus RC(O)OOH, OOH, OOH, OO, OO.
- RC(O)OOH and RC(O)OOH bond energies are ∼13 and 10 kcal mol−1 stronger than in RCOOH.
- RC(O)OO bonds are about 10 kcal mol−1 weaker; R groups phenyl, vinyl, allyl and alkyl.