Article ID Journal Published Year Pages File Type
5380080 Chemical Physics Letters 2015 5 Pages PDF
Abstract

- Hydrogen release from SiH4 and CH3SiH3 in presence of BH3/AlH3 is a facile process.
- Reactions of silanes with BH3 are more favorable than those with AlH3.
- Addition of an extra BH3 yields low energy barriers for dehydrogenation pathways.
- Additional BH3 Lewis acid plays the role of a bi-functional catalyst.
- Silanes can be used as starting materials for chemical hydrogen storage.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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